Alex Guenther
Senior Scientist
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Project Summary:
BEACHON-CHATS: A classic micrometeorology experiment augmented to evaluate novel sensing approaches for couples BHA science. (TIIMES-ACD-WOL-MMM-Duke University Collaboration) FY07 TIIMES research focused on understanding and quantifying biosphere-atmosphere exchange of trace gases and aerosols. This included field studies (Eucalyptus Forest Aerosols and Precursors, EUCAP in Australia and CHATS in California), laboratory studies (FL0 greenhouse and chamber facilities), and modeling studies. Additional efforts were focused on the development of the BEACHON research project.
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BEACHON-CHATS: It's Green! This research resulted in the discovery of a new class of compounds that may be important biogenic emissions into the atmosphere. The compounds are called salates and serve as sunscreen protection in some plants. They were previously thought to be non-volatile. In addition, it was demonstrated that current atmospheric modeling approaches greatly underestimate OH concentrations over tropical forests. This has major implications for atmospheric chemistry and could explain why models overestimate ambient biogenic VOC concentrations when using our recommended biogenic emission rates. Finally, these studies show that U.S. air quality will likely degrade in the future due to increases in wildfire and biogenic emissions and from pollutant transport from other countries. FY08 TIIMES research will be focused on initiating the BEACHON project. This will include field, laboratory and modeling studies. |
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Community Service:
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Presentations:
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TIIMES External Collaborators:
Jonathan Adams, Rutgers University |
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Publications:Harley, P., J. Greenberg, Ulo. Niinemets, A. Guenther, 2007: Environmental controls over methanol emission from leaves. Biogeosciences Discuss., 4, 2593-2640. Karl, T., A. Guenther, R. J. Yokelson, J. Greenberg, M. Potosnak, D. R. Blake, P. Artaxo, 2007: The tropical forest and fire emissions experiment: Emission, chemistry, and transport of biogenic volatile organic compounds in the lower atmosphere over Amazonia. J. Geophys. Res., American Geophysical Union, 112, D18302, doi: 10.1029/2007JD008539. Ortega, J., D. Helmig, A. Guenther, P. Harley, S. Pressley, C. Vogel, 2007: Flux estimates and OH reaction potential of reactive biogenic volatile organic compounds (BVOCs) from a mixed northern hardwood forest. Atmos. Environ., Elsevier Ltd., 41, 5479-5495, doi: 10.1016/j.atmosenv.2006.12.033. Karl, T. G., T. J. Christian, R. J. Yokelson, P. Artaxo, W. M. Hao, A. Guenther, 2007: The tropical forest and fire emissions experiment: method evaluation of volatile organic compound emissions measured by PTR-MS, FTIR, and GC from tropical biomass burning. Atmos. Chem. Phys. Discuss., 7, 8755-8793. Matsunaga, S. N., A. B. Guenther, Y. Izawa, C. Wiedinmyer, J. P. Greenberg, K. Kawamura, 2007: Importance of wet precipitation as a removal and transport process for atmospheric water soluble carbonyls. Atmos. Environ., 41, 790-796, doi: 10.1016/j.atmosenv.2006.08.054. Shim, C., Y. Wang, H. B. Singh, D. R. Blake, A. B. Guenther, 2007: Source characteristics of oxygenated volatile organic compounds and hydrogen cyanide. J. Geophys. Res., 112, D10305, doi: 10.1029/2006JD007543. Yokelson, R. J., T. Karl, P. Artaxo, D. R. Blake, T. J. Christian, D. W. T. Griffith, A. Guenther, W. M. Hao, 2007: The Tropical Forest and fire emissions experiment: overview and airborne fire emission factor measurements. Atmos. Chem. Phys. Discuss., 7, 6903-6958. Donkelaar, A. V., R. V. Martin, R. J. Park, C. L. Heald, T.-M. Fu, H. Liao, A. Guenther, 2007: Model evidence for a significant source of secondary organic aerosol from isoprene. Atmos. Environ., 41, 1267-1274, doi: 10.1016/j.atmosenv.2006.09.051. Stroud, C. A., A. Nenes, J. L. Jimenez, P. F. DeCarlo, J. A. Huffman, R. Bruintjes, E. Nemitz, A. E. Delia, D. W. Toohey, A. B. Guenther, S. Nandi, 2007: Cloud activating properties of aerosol observed during CELTIC. J. Atmos. Sci., American Meteorological Society, 64 (2), 441-459, doi: 10.1175/JAS3843.1. Helmig, D., J. Ortega, T. Duhl, D. Tanner, A. Guenther, P. Harley, C. Wiedinmyer, J. Milford, T. Sakulyanontvittaya, 2007: Sesquiterpene emissions from Pine Trees - Identifications, Emission Rates and Flux Estimates for the Contiguous United States. Environ. Sci. Technol., 41, 1545 -1553, doi: 10.1021/es0618907. |
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